Pentafluoroethane
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Names | |||
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Preferred IUPAC name Pentafluoroethane | |||
Other names Pentafluoroethane, Genetron HFC 125, Khladon 125, Suva 125, Freon 125, Fc-125, R-125 | |||
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ECHA InfoCard | 100.005.962 ![]() | ||
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Properties | |||
Chemical formula | C2HF5 | ||
Molar mass | 120.02 g/mol | ||
Appearance | Colourless gas. Has a faint, almost imperceptible odor | ||
Density | 1.53 g/cm3 (liquid at −48.5 °C)[1] | ||
Melting point | −103.0 °C (−153.4 °F; 170.2 K) | ||
Boiling point | −48.5 °C (−55.3 °F; 224.7 K) | ||
Vapor pressure | 1414.05 kPa (at 25 °C) | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). ![]() ![]() ![]() Infobox references |
Pentafluoroethane is a fluorocarbon with the formula CF3CHF2. Pentafluoroethane is currently used as a refrigerant (known as R-125) and also used as a fire suppression agent in fire suppression systems.
Pentafluoroethane does not deplete ozone so it has replaced earlier fluorinated chemicals that did. However while it has zero ozone depletion potential, it has high global warming potential, reported by the United States Environmental Protection Agency (EPA) as 3450 times that of carbon dioxide.[2]
Refrigerant
![](http://upload.wikimedia.org/wikipedia/commons/thumb/e/e1/Container_%E3%80%90_2079_%E3%80%91_CCRU_538017%280%29_%E3%80%90_Pictures_taken_in_Japan_%E3%80%91.jpg/220px-Container_%E3%80%90_2079_%E3%80%91_CCRU_538017%280%29_%E3%80%90_Pictures_taken_in_Japan_%E3%80%91.jpg)
Pentafluoroethane in a near azeotropic mixture with difluoromethane is known as R-410A, a common replacement for various chlorofluorocarbons (commonly known as Freon) in new refrigerant systems.
Fire suppression systems
HFC-125 (ECARO-25 / FE-25 / NAF S 125) is a gaseous fire suppression agent which can be used in clean agent fire suppression systems. In addition, HFC-125 leaves no residue on valuable equipment and material after discharge.[3] It is generally used in situations where water from a fire sprinkler would damage expensive equipment, or where water-based fire protection is impractical, such as museums, banks, clean rooms and hospitals. The HFC-125 clean agent is stored in a pressurized container and introduced into the hazard as a gas. The agent is odorless, colorless, electrically non-conductive, non-corrosive, and leaves no residue. It is used in occupied enclosed areas that contain high-value assets.
HFC-125 suppresses fire by absorbing heat energy at its molecular level faster than the heat can be generated, so the fire cannot sustain itself. It also forms free radicals to chemically interfere with the chain reaction of the combustion process. This makes it a highly effective fire fighting agent that is safe for people and causes no damage to equipment.
HFC-125 is considered a Clean Agent and is therefore included in the National Fire Protection Association's 2001 - Standard for Clean Agent Fire Extinguishing Systems.
Environmental impact
![](http://upload.wikimedia.org/wikipedia/commons/thumb/1/1e/HFC-125_mm.png/260px-HFC-125_mm.png)
![](http://upload.wikimedia.org/wikipedia/commons/thumb/b/b2/HFC125_concentration.jpg/220px-HFC125_concentration.jpg)
HFC-125 is a non-ozone depleting replacement for chlorine- or bromine-containing chemicals such as Halon 1301. Due to its global warming potential (GWP) of 3500 times that of CO₂ and atmospheric lifetime of 29 years, it is included in the list of controlled substances of the Montreal Protocol.[4][5]
When introduced to the market HFC-125 was not considered safe for use in occupied spaces. The US EPA Significant New Alternative Policy (SNAP) listing reflected this. Following the introduction and acceptance of the PBPK model in the NFPA standard 2001 on Clean Agent Fire Extinguishing Systems 2004 Edition, the restriction was relaxed and now HFC-125 can be used in occupied hazards. Generally, class B (flammable liquid) hazards require concentrations that exceed the agent's no-observed-adverse-effect level (NOAEL) so extra precautions must be taken to avoid prolonged exposure to the agent.
At high temperatures, pentafluoroethane will decompose and produce hydrogen fluoride. This is observable as presence of sharp, pungent odour, which can be perceived in concentrations far below a dangerous level. Other decomposition products include carbonyl fluoride, carbon monoxide and carbon dioxide. Prior to re-entry of a room where HFC-125 system has been activated to suppress a fire, the atmosphere should be tested. An Acid Scavenging Additive added to pentafluoroethane is able to reduce the amount of hydrogen fluoride.
Brands
ECARO-25 is a registered trademark of Fike Corporation. FE-25 is a registered trademark of E. I. du Pont de Nemours and Company or its affiliates. NAF S 125 (HFC-125 plus Acid Scavenging Additive) is a trademark of Safety Hi-Tech.
References
- ^ Kirk-Othmer Encyclopedia of Chemical Technology. Wiley. ISBN 9780471238966.
- ^ "Protection of Stratospheric Ozone: Notice 20 for Significant New Alternatives Policy Program". Federal Register Environmental Documents. Environmental Protection Agency. March 29, 2006. Archived from the original on 29 Jul 2012.
- ^ "ECARO-25® Clean Agent Fire Suppression - HFC-125". Fike. Archived from the original on Aug 6, 2020.
- ^ Montreal Protocol Section 1.1. including 2016 Kigali amendment (in effect in 2019)
- ^ P. Forster; V. Ramaswamy; P. Artaxo; T. Berntsen; R. Betts; D.W. Fahey; J. Haywood; J. Lean; D.C. Lowe; G. Myhre; J. Nganga; R. Prinn; G. Raga; M. Schulz; R. Van Dorland (2007). "Chapter 2: Changes in Atmospheric Constituents and in Radiative Forcing". In Solomon, S.; Miller, H.L.; Tignor, M.; Averyt, K.B.; Marquis, M.; Chen, Z.; Manning, M.; Qin, D. (eds.). Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge, United Kingdom and New York, NY, USA: Cambridge University Press. Archived from the original on 1 December 2016. Retrieved 9 October 2016.
- "Pentafluoroethane (CASRN 354-33-6)". Integrated Risk Information System. United States Environmental Protection Agency. Archived from the original on Oct 26, 2012.
- "NAF® S 125". Safety Hi-Tech. Archived from the original on Oct 7, 2022.
- "ECARO-25 fire suppression systems". Fike. Archived from the original on Jan 22, 2009.
- "Protecting What Matters Most With DuPont™ FE-25™". DuPont. Archived from the original on 2015-04-28.
- "FE25 - HFC125 Extinguishing System". Sinerji Yangın ve Güvenlik Sistemleri. Archived from the original on Apr 29, 2021.
External links
- Safety MSDS data