Thiostannate
Sulfidostannates, or thiostannates are chemical compounds containing anions composed of tin linked with sulfur. They can be considered as stannates with sulfur substituting for oxygen. Related compounds include the thiosilicates, and thiogermanates, and by varying the chalcogen: selenostannates, and tellurostannates. Oxothiostannates have oxygen in addition to sulfur.[1] Thiostannates can be classed as chalcogenidometalates, thiometallates, chalcogenidotetrelates, thiotetrelates, and chalcogenidostannates. Tin is almost always in the +4 oxidation state in thiostannates, although a couple of mixed sulfides in the +2 state are known,
Some thiostannate minerals are known. In nature the tin can be partly replaced by arsenic, germanium, antimony or indium. Many thiostannate minerals contain copper, silver or lead. In the field of mineralogy, these compound can be termed sulfostannates or sulphostannates.
Different cluster anions are known: [SnS4]4–, [SnS3]2–, [Sn2S5]2–, [Sn2S6]4–, [Sn2S7]6–, [Sn2S8]2–, [Sn3S7]2–, [Sn4S9]2–, [Sn5S12]4–, or [Sn4S10]4–.[2]
The number of sulfur atoms coordinated around the tin atom is most commonly four. However there are also complexes with five or six sulfur atoms surrounding the tin. The behaviour for selenium and tellurium differs as only five selenium or four tellurium atoms can bind to a tin atom. The smaller germanium atom can only accommodate four sulfur atoms. For lead it is hard for it to be in the +4 oxidation state. The SnSn polyhedrons can be standalone in strongly alkaline conditions, or at higher concentrations or less alkaline can condense together. Polyhedra shapes are tetrahedron for four, trigonal bipyramid for five, and octahedron for six sulfur atoms. The polyhedra can be connected at a vertex (corner), or at an edge. Where connected at an edge, four membered rings of -SnSSnS- with internal angles close to 90°.[3] [Sn2S7]6– is corner bridged. Tetrahedra linked by at the corner by a disulfur bridge are unknown.[3]
Sn10O4S208- is a supertetrahedron made from 1, 3 and 6 tin atoms connected by oxygen on the interior and sulfur on the surface.[3]
For anions with formula SnxSy the condensation ratio c is given by 1/2.[3]
Synthesis
The first human production of a thiostannate heated tin oxide with sodium carbonate and sulfur:[4]
2SnO2 + 2Na2CO3 + 9S → 2Na2SnS3 + 2CO2 + 3SO2
Transition metal complexes may be prepared by crystallisation from the ligand solvent.[4]
Copper(II) is normally reduced by sulfide S2- in thiostannates to copper(I).[5]
Anions
formula | name | coordination | dimensionality | description |
---|---|---|---|---|
[SnS4]4− | 4 | 0 | tetrahedra | |
[Sn2S6]4− | bis(μ-sulfido)-tetrathiolato-di-tin | 4 | 0 | edge shared |
[Sn3S9]6− | 1,3,5,2,4,6-trithiatristanninane-2,2,4,4,6,6-hexakis(thiolate) | 4 | 0 | 6 membered ring |
[Sn4S10]4- | 4 | 0 | tetrameric adamantane-like : tetrahedron of tetrahedra, 6 bridging sulfur, 4 terminal sulfur |
Reactions
Some hydrates are unstable, where water reacts with the sulfide to make hydrogen sulfide gas.
List
formula | system | space group | unit cell Å | volume | density | comment | |
---|---|---|---|---|---|---|---|
Li4SnS4 | orthorhombic | Pnma | a=13.812 b=7.962 c=6.370 | [6] | |||
[Li8(H2O)29][Sn10O4S20]·2H2O | triclinic | P1 | a = 11.232, b = 13.097, c = 23.735, α = 102.73°, β = 90.43°, γ = 93.44°, Z = 2 | 3399 | oxothiostannate | [7] | |
(NH4)4Sn2S6·3H2O | orthorhombic | P41212 | a =8.56294 b =8.56294 c= 22.7703 | [8] | |||
(NH4)6Sn3S9·1.3H2O | monoclinic | C2 | a 16.9872 b 10.54777 c 21.0871 β 108.0389° | 3592.6 | 2.154 | colourless | [9] |
[(CH3)3NH]2Sn3S7 | [3] | ||||||
[(CH3)4N]2Sn3S7·H2O | [3] | ||||||
[(CH3)4N]4Sn4S10 | [8] | ||||||
[(CH3CH2)4N]2Sn3S7 | [3] | ||||||
[(CH3CH2CH2)4N]2Sn4S9 | [3] | ||||||
[(CH3CH2CH2CH2)4N]2Sn4S9 | [3] | ||||||
[(CH3CH2CH2)4N][(CH3)3NH]Sn4S9 | [3] | ||||||
(C12H25NH3)4Sn2S6 ·2H2O | [3] | ||||||
[dabcoH]2Sn3S7 | [3] | ||||||
(Et4N)2Sn(S4)3 | [3] | ||||||
(Et4N)2Sn(S4)2(S6) | [3] | ||||||
((CH3C(NH2)2)8Sn2S6SnS4 | monoclinic | C 1 2/m 1 | a=23.7739 b=16.0647 c=11.8936 β=99.029 Z=4 | 4486.1 | 1.702 | colourless | [9] |
((CH3)2NH2)(NH4)SnS3 dimethylammonium ammonium | orthorhombic | P212121 | a=5.9393 b=12.1816 c=12.4709 Z=4 | 902.26 | 2.054 | colourless | [9] |
(DBNH)2Sn3S6 DBN=1,5-diazabicyclo[4.3.0]non-7-ene | Sn(II) and Sn(IV) | [10] | |||||
(1AEP)2Sn3S7 1AEP = 1-(2-aminoethyl) piperidine | orthorhombic | P212121 | a=13.2299 b= 22.2673 c=9.0772 Z=4 | 2674.1 | pale yellow | [11] | |
SnS2·en | monoclinic | C2/c | a 15.317 b 10.443 c 12.754, β 93.62° | [12] | |||
[enH]4[Sn2S6]·en | triclinic | P1 | a 9.8770 b 9.9340 c 15.4230, α 72.630° β 86.220° γ 81.380° | [12] | |||
Na2SnS3 | R3m | a=3.834 c=19.876 Z=2 | 253 | 3.43 | [4][13] | ||
Na4SnS4 | tetragonal | P421c | a=7.837 c=6.950 | 427 | 2.64 | [13] | |
Na4Sn2S6 | [3] | ||||||
Na4Sn2S6·14H2O | triclinic | P1 | a=10.114 b=7.027 c=9.801 α=108.30 β=92.18 γ=91.11 Z=1 | 663 | 1.95 | [2] | |
Na4SnS4·14H2O | monoclinic | C2/c | a=8.622 b=23.534 c=11.347 β=110.53 Z=4 | 2156 | 1.82 | [13] | |
Na4Sn3S8 | [3] | ||||||
Na5[SnS4]Cl·13H2O | monoclinic | P21/m | a=8.4335 b=11.4958 c=11.5609 β=91.066 Z=2 | 1120.63 | 1.872 | [2] | |
Na4Sn2S6·5H2O | [3] | ||||||
Na6Sn2S7 | C2/c | a=9.395 b=10.719 c=15.671 β=109.97 Z=4 | 1483 | 2.69 | [13] | ||
Mg2SnS4 | orthorhombic | Pnma | a=12.93 b=7.52 c=6.16 Z=4 | 599 | 3.28 | [13] | |
Na2MgSnS4 | R3m | a 3.7496 b 3.7496 c 19.9130 | [14] | ||||
(Ph4P)2Sn(S4)3 | [3] | ||||||
K2SnS3 ·2H2O | [3] | ||||||
K2SnS3·2H2O | orthorhombic | Pnma | a=6.429 b=15.621 c=10.569 Z=4 | 1061 | 2.06 | [13] | |
K2Sn2S5 | [3] | ||||||
K2Sn3S7 ·H2O | [3] | ||||||
[K4(H2O)4][SnS4] | [15] | ||||||
Ca2SnS4 | orthorhombic | Pnma | a=13.74 b=8.23 c=6.44 Z=4 | 728 | 2.99 | [13] | |
[H2tepa][VIII(tepa)(μ-Sn2Q6)]2 | orthorhombic | Abm2 | a =7.7486 b =40.410 c =16.745 | [16] | |||
Mn2SnS4 | tetragonal | I41/a | a=7.408 c=10.41 Z=8 | 571 | 4.15 | [13] | |
[Mn(en)3]2[Sn2S6] | monoclinic | C2/c | a=15.138 b=10.6533 c=23.586 β=118.42 Z=4 | 3345.2 | 1.787 | colourless | [5][17] |
[Mn(en)3]2Sn2S6·2H2O | monoclinic | P21/c | a=10.129, b=15.746, c=11.524, β=102.36° Z=2 | 1795.5 | 1.732 | [18] | |
[Mn(en)2]2(μ-en)[Sn2S6] | triclinic | a=9.0017 b=9.7735 c=10.8421 α=60.38° β=67.23° γ=70.25° | 752.38 | [16] | |||
[Mn(dien)2]2Sn2S6 | monoclinic | P21/c | a=12.48 12, b= 9.3760, c=17.7617, β=121.752°, Z=2, | 1767.5 | 1.789 | [18] | |
[Mn(tren)]2Sn2S6 | triclinic | P1 | a 7.653 b 8.088 c 12.200, α 97.27° β 104.06° γ 108.80° Z=1 | 676.0 | 2.044 | yellow | [5][19] |
[Mn(tren)(H2O)][Mn(baen)]3Mn4Sn6S20∙9H2O | orthorhombic | P213 | a =21.404 b =21.404 c= 21.404 | super tetrahedron | [20] | ||
{Mn(tepa)}2(μ-Sn2S6) | tetragonal | I41/a | a=25.977 c=10.041 Z=8 | 6775 | 1.800 | yellow | [19] |
{[Mn(trien)]2[SnS4]} | [5] | ||||||
{[Mn(C6H18N4)]2SnS4}·4H2O | monoclinic | P21/c | a 10.8446 b 20.974 c 13.2746 β 113.487° | [21] | |||
{[Mn(phen)2]2(μ2-Sn2S6)} | monoclinic | P21/n | a =10.8230 b=9.8940 c=24.811 β=91.356° | [22] | |||
{[Mn(phen)2]2(μ2-Sn2S6)}·phen | triclinic | P1 | a=10.0642 b=10.6249 c=13.693, α=71.700° β=81.458° γ=84.346° | [22] | |||
{[Mn(phen)2]2[Sn2S6]}·phen·H2O phen = 1,10-phenanthroline | triclinic | P1 | a=11.3203 b=12.1436 c=12.7586, α=113.200° β=90.908° γ=110.974° | [5][22] | |||
[Mn(phen)]2(SnS4)·H2O | monoclinic | C2/m | a=16.146 b=19.262 c=9.938 β=124.970 Z=4 | 2532.6 | 1.928 | red chain | [23] |
{[Mn(phen)2]2[μ-η2-η2-SnS4]2[Mn(phen)]2}·H2O | triclinic | P1 | a=10.8703 b=12.5183 c=14.9644, α=103.381° β=108.390° γ=101.636° | [22] | |||
{[Mn(2,2′-bipy)2]2[Sn2S6]} | [24] | ||||||
(1,4-dabH)2MnSnS4 1,4-dab = 1,4-diaminobutane | orthorhombic | Fdd2 | a = 22.812, b = 24.789, c = 6.4153, Z = 8 | 3627.8 | [25] | ||
Li4MnSn2Se7 | monoclinic | Cc | a=18.126 b=7.2209 c=10.740 β=93.43 Z=4 | 1403.2 | 4.132 | orange | [26] |
Fe2SnS4 | tetragonal | I41/a | a=7.308 c=10.338 Z=4 | 552 | 4.32 | [13] | |
{[Fe(tepa)]2[Sn2S6]} | tetragonal | I41/a | [5][27] | ||||
{[Fe(1,2-dach)2][Sn2S6]}·2(1,2-dachH) | [5] | ||||||
{[Fe(phen)2]2[Sn2S6]}·phen·H2O | [5] | ||||||
[Co(en)3]2[Sn2S6] | orthorhombic | Pbca | a=15.640 b=11.564 c=18.742 Z=4 | 2289.7 | 1.779 | yellow | [5][17] |
[Co(dien)2]2[Sn2S6] | [5] | ||||||
[Co2(cyclam)2Sn2S6]·2H2O | [28] | ||||||
[Co(tren)]2Sn2S6 | monoclinic | C2/c | a=12.228 b=9.7528 c=23.285 β=102.90 | 2706.8 | [5][16] | ||
{[Co(cyclam)]2[Sn2S6]}n·2nH2O cyclam = 1,4,8,11-tetraazacyclotetradecane | [5] | ||||||
{[Co(tepa)]2[Sn2S6]} tepa=tetraethylenepentamine | tetragonal | I41/a | a=25.742 c=9.898 | 6558 | [5][27][16] | ||
{[Co(phen)2]2[Sn2S6]}·phen·H2O | [5] | ||||||
[Co(2-(aminomethyl)pyridine)3]2Sn2S6·10H2O (2amp) | monoclinic | P21/c | a=10.1443 b=14.6124 c=18.8842 β=90.601° Z=2 | 2799.1 | 1.633 | yellow | [29] |
[Co(trans-1,2-diaminocyclohexane)3]2Sn2S6·8H2O (dach) | monoclinic | P21/n | a=12.6521 b=11.7187 c=20.4386 β=91.262° Z=2 | 3029.6 | 1.509 | red | [29] |
Ni6SnS2 Butianite | tetragonal | I4/mmm | a = 3.650, c = 18.141 Z=2 | 241.7 | 7.62 | opaque | [30] |
[Ni(en)3]2[Sn2S6] | [5] | ||||||
[Ni(dap)3]2[Sn2S6]·2H2O dap=1,2-diaminopropane | triclinic | P1 | a=9.9046 b=10.527 c=11.319 α =72.13° β =85.19° γ =63.63° | 1004.5 | [5][16] | ||
[Ni(1,2-dach)3]2[Sn2S6]·4H2O 1,2-dach = 1,2-diaminocyclohexane | [5] | ||||||
[Ni(dien)2]2[Sn2S6] | [5] | ||||||
{[Ni(cyclen)]6[Sn6S12O2(OH)6]}·2(ClO4)·19H2O cyclen = 1,4,7,10-tetraazacyclododecane | [31] | ||||||
[Ni(cyclen)(H2O)2]4[Sn10S20O4]·~13H2O | [31] | ||||||
{[Ni(cyclen)]6[Sn6S12O2(OH)6]}·2(ClO4)·19H2O | monoclinic | C2/c | a=25.7223 b=15.6522 c=29.070 β=105.879 Z=4 | 11257 | 1.863 | oxothiostannate | [32] |
[Ni(2amp)3]2[Sn2S6]·9.5H2O 2amp = 2-(aminomethyl)pyridine | monoclinic | P21/n | a=18.7021 b=14.6141 c=20.2591 β=97.696 Z=4 | 5487.2 | 1.655 | purple | [4] |
[Ni(aepa)2]2[Sn2S6] aepa=N-2-aminoethyl-1,3-propandiamine | [5] | ||||||
[Ni(tren)]2Sn2S6 | monoclinic | C2/c | a=23.371 b=8.231 c=14.274 β =107.230 Z=4 | 2622.6 | 2.127 | [5][33] | |
[Ni(tren)2]2[Sn2S6]·8H2O | orthorhombic | P42/n | a=26.1885 b=26.1885 c=11.1122 | [5][34] | |||
[Ni(tren)(2amp)]2[Sn2S6] | triclinic | P1 | a =10.2878 b =11.1100 c =11.4206, α =84.740° β =84.395° γ =79.093° | [5][34] | |||
[Ni(tren)(2amp)]2[Sn2S6]·10H2O | monoclinic | P21/n | a =12.1933 b =13.4025 c =14.8920 β= 103.090° | [35] | |||
[Ni(tren)(en)]2[Sn2S6]·2H2O | monoclinic | P21/n | a 12.7041 b 9.8000 c 15.3989, β 108.843° | [35] | |||
[Ni(tren)(en)]2[Sn2S6]·6H2O | monoclinic | P21/n | a 12.5580 b 9.7089 c 16.0359, β 91.827° | [35] | |||
[Ni(tren)(1,2-dach)]2[Sn2S6]·3H2O | triclinic | P1 | a 9.8121 b 10.0080 c 12.422, α 86.38° β 79.65° γ 65.72° | [35] | |||
[Ni(tren)(1,2-dach)]2[Sn2S6]·4H2O | monoclinic | P21/n | a 10.7119 b 19.0797 c 11.1005, β 104.803° | [35] | |||
{[Ni(cyclam)]2[Sn2S6]}·2H2O | [5] | ||||||
{[Ni(tepa)]2[Sn2S6]} | monoclinic | P21/n | [5][27] | ||||
{[Ni(phen)2]2[Sn2S6]}·2,2′-bipy | monoclinic | P21/n | a=10.5715 b=9.9086 c=24.9960 β=92.800 Z=2 | 2615.17 | 1.809 | deep red | [5][36] |
{[Ni(phen)2]2Sn2S6}·4,4′-bipy·½H2O 4,4′-bipy = 4,4′-bipyridine | monoclinic | C2/c | a=18.3431 b=19.4475 c=15.0835 β=95.556 Z=4 | 5355.4 | 1.789 | dark red-brown | [36] |
{[Ni(phen)2]2[Sn2S6]}·phen·H2O | [24] | ||||||
[Ni(L1)][Ni(L1)Sn2S6]n·2H2O L1 = 1,8-dimethyl-1,3,6,8,10,13-hexaazacyclotetradecane | monoclinic | P21/c | [37] | ||||
[Ni(L2)]2[Sn2S6]·4H2O L2 = 1,8-diethyl-1,3,6,8,10,13-hexaazacyclotetradecane | triclinic | P1 | [37] | ||||
[Ni(tren)(ma)(H2O)]2[Sn2S6]·4H2O ma = methylamine | monoclinic | P21/n | a=11.1715 b=10.5384 c=15.8594 Z=2 | 1827.45 | 1.835 | [33] | |
[Ni(tren)(1,2-dap)]2[Sn2S6]·2H2O | monoclinic | P21/n | a=12.9264 b=10.1627 c=15.6585 Z=2 | 1889.8 | 1.799 | [33] | |
[Ni(tren)(1,2-dap)]2[Sn2S6]·4H2O | monoclinic | C2/c | a =14.3925 b=15.1550 c=18.9307, β=99.108° | [35] | |||
[Ni(2amp)3]2[Sn2S6]·9.5H2O 2amp = 2-(aminomethyl)pyridine | monoclinic | P21/n | a=18.7021 b=14.6141 c=20.2591 Z=4 | 5487.23 | 1.655 | purple | [4] |
Cu2SnS3 Mohite | monoclinic | a=23.10 b=6.25 c=6.25 β=101.0° | 4.69 | greenish grey | [13][38] | ||
Cu3SnS4 Kuramite | tetragonal | I42m | a = 5.445, c = 10.75, Z = 2 | 318.72 | 4.56 | [39] | |
Cu4SnS4 | orthorhombic | Pnma | a=13.70 b=7.750 c=6.454 Z=4 | 685 | 4.96 | [13] | |
Cu4SnS6 Erazoite | rhombohedral | R3m | a = 3.739, c = 32.941, Z = 2 | 4.53 | black | [40] | |
Cu4Sn7S16 | monoclinic | a=12.75 b=7.34 c=12.71 β=109.5 Z=2 | 1121 | 4.74 | [13] | ||
(DBUH)CuSnS3 DBU = 1,8-diazabicyclo[5.4.0]undec-7-ene | monoclinic | P21/n | a=9.254 b=8.6190 c=18.135, β=92.80° | [41] | |||
(1,4-dabH2)Cu2SnS4 1,4-dab = 1,4-diaminobutane | tetragonal | P42/n | a=14.539 c=11.478 | [42] | |||
(enH)6Cu40Sn15S60 en=ethylenediamine | cubic | Pn3n | a=25.260 Z=4 | 16119 | 2.727 | black | [43] |
(enH)3Cu7Sn4S12 | trigonal | R3c | a=13.532 c=28.933 Z=6 | 4588 | 3.23 | red | [43] |
[H2en]2[Cu8Sn3S12] | [5] | ||||||
(trenH3)Cu7Sn4S12 tren = tris(2-aminoethyl)amine) | trigonal | R3c | a=13.1059 c=29.347 Z=6 | 4365.4 | 3.317 | [43] | |
[dienH2][Cu2Sn2S6] | [5] | ||||||
[DBUH][CuSnS3] DBU = 1,8-diazabicyclo[5.4.0]undec-7-ene | [5] | ||||||
[1,4-dabH2][Cu2SnS4] | [5] | ||||||
{[Cu(cyclam)]2[Sn2S6]}·2H2O cyclam=1,4,8,11-tetraazacyclotetradecane | triclinic | P1 | a=9.0580 b=9.9419 c=10.2352, α=97.068° β=94.314° γ=101.514° | [5] | |||
(DBNH)2Cu6Sn2S8 DBN=1,5-diazabicyclo[4.3.0]non-7-ene | [10] | ||||||
[Co(2-(aminomethyl)pyridine)3]2 Sn2S6·10H2O | monoclinic | P21/c | a=10.1443 b=14.6124 c=18.8842 β=90.601° Z=2 | 2799.1 | 1.633 | yellow; unstable | [44] |
[Co(trans-1,2-diaminocyclohexane)3]2Sn2S6·8H2O | monoclinic | P21/n | a=12.6521 b=11.7187 c=20.4386 β=91.262° Z=2 | 3029.6 | 1.509 | red | [44] |
Na4Cu32Sn12S48·4H2O | cubic | Fm3c | a = 17.921 z = 13 | black; absorption edge 2.0 eV | [45] | ||
CuAlSnS4 | cubic | a=10.28 Z=8 | 1074 | 4.17 | [13] | ||
K11Cu32Sn12S48·4H2O | cubic | Fm3c | a = 18.0559 z = 14.75 | black; absorption edge 1.9 eV | [45] | ||
Cu2MnSnS4 | tetragonal | a=5.49 c=10.72 Z=2 | 323 | 4.41 | [13] | ||
Cu2FeSnS4 Stannite Ferrokësterite | tetragonal | I42m | a = 5.4432, c = 10.7299 Z=2 | 317.91 | grey | [46] | |
Cu2FeSn3S8 | tetragonal | I41/a | a=7.29 c=10.31 Z=2 | 548 | 4.82 | [13] | |
Cu6Fe2SnS8 Mawsonite | Tetragonal | P4m2 | a = 7.603, c = 5.358 Z=1 | 309 | 4.65 | brownish orange | [47] |
Cu6FeSn2S8 Chatkalite | Tetragonal | P4m2 | a = 7.61, c = 5.373 Z=1 | 311.1 | 5.00 | [48] | |
Cu2CoSnS4 | Tetragonal | I42m | a=5.402 c=10.805 Z=2 | 315 | 4.56 | [13] | |
Cu2NiSnS4 | a=5.425 Z=1 | 160 | 4.49 | [13] | |||
Cu13VSn3S16 Nekrasovite | isometric | a=10.73 | 1,235 | brown | [49] | ||
[Zn(en)3]2[Sn2S6] | orthorhombic | Pbca | a=15.452 b=11.524 c=18.614 Z=4 | 3315.3 | 1.845 | colourless | [5][17] |
{Zn(tren)}2(μ-Sn2S6) | monoclinic | C2/c | a 12.214 b 9.726 c 23.209 β 102.732° | 2689.3 | 2.107 | light yellow | [19][50] |
Cu2ZnSnS4 Kësterite | tetragonal | I4 | a = 5.427, c = 10.871 Z=2 | 320.18 | 4.55 | greenish black | [51] |
Cu6+Cu22+(Fe2+,Zn)3Sn2S12 Stannoidite | orthorhombic | a = 10.76, b = 5.4, c = 16.09 | 934.9 | 4.68 | brass | [52] | |
Cu3(V,Ge,Sn)S4 Ge-Sn-Sulvanite | 361 | [53] | |||||
SnGeS3 Stangersite | monoclinic | P21/b | a = 7.270, b = 10.197, c = 6.846 β = 105.34° Z=4 | 489 | 3.98 | orange | |
Rb4SnS4 | [3] | ||||||
Rb4Sn2S6 | [3] | ||||||
Rb2Sn3S7·2H2O | [3] | ||||||
Rb2Cu2SnS4 | orthorhombic | Ibam | a=5.528 b=11.418 c=13.700 Z=4 | 865 | 4.185 | band gap 2.08 eV | [54] |
Rb2Cu2Sn2S6 | monoclinic | C2/c | a=11.026 b=11.019 c=20.299 β=97.79 Z=8 | 2444 | 3.956 | band gap 1.44 eV | [54] |
Rb2ZnSn3S8 | [55] | ||||||
[Rb4(H2O)4][SnS4] | [15] | ||||||
Sr3MnSn2S8 | cubic | I43d | a = 14.2287 Z = 8 | 2880.7 | 3.743 | dark green | [56] |
Cu2SrSnS4 | trigonal | P31 | a = 6.29, c = 15.57 Z=3 | 534 | 4.31 | [57][13] | |
Sr6Cu4Sn4S16 | cubic | I43d | a=13.982 | 2734 | 4.295 | yellow | [58] |
Sr6Cu2FeSn4S16 | cubic | I43d | a=14.1349 | band gap 1.53 eV | [59] | ||
SrSnS3 | orthorhombic | Pnma | a=8.264 b=3.867 c=14.116 Z=4 | 451 | 4.45 | [13] | |
[Y2(dien)4(μ-OH)2]Sn2S6 | monoclinic | P21/n | a=11.854 b=11.449 c=13.803 β=97.978 Z=2 | 1855 | 1.888 | light yellow | [60] |
α-Ag8SnS6 | cubic | a=21.43 | 9842 | [13] | |||
β-Ag8SnS6 | cubic | a=10.85 | 1277 | [13] | |||
Ag8SnS6 Canfieldite | orthorhombic | a = 15.298, b = 7.548, c = 10.699 Z=4 | 1,235.4 | 6.311 | metallic | [61] | |
Na3AgSnS4 | monoclinic | P21/c | a 8.109 b 6.483 c 15.941, α 90° β 103.713 | double chain | [62] | ||
AgCrSnS4 | cubic | a=10.74 Z=8 | 1239 | 4.92 | [13] | ||
Ag2MnSnS4 – Agmantinite | orthorhombic | a = 6.632, b = 6.922, c = 8.156 Z=2 | 4.574 | orange | [63] | ||
Ag2ZnSnS4 Pirquitasite | tetragonal | I4 | a = 5.78, c = 10.82 | 361 | black | [64] | |
Ag2(Fe2+,Zn)SnS4 Hocartite | tetragonal | I42m | a = 5.74, c = 10.96 Z=2 | 361 | 4.77 | brownish grey | [65] |
Ag1+(Fe2+0.5Sn4+1.5)S4 Toyohaite | tetragonal | grey | [66] | ||||
[enH][Cu2AgSnS4] | orthorhombic | Pnma | a=19.7256 b=7.8544 c= 6.5083 Z=4 | 1008.3 | 3.577 | red | [67] |
Ag2SrSnS4 | orthorhombic | a=7.127 b=8.117 c=6.854 Z=2 | 397 | 5.02 | [13] | ||
Sr6Ag4Sn4S16 | cubic | I43d | a=14.2219 Z=4 | 2876.6 | 4.491 | yellow | [58] |
Sr6Ag2FeSn4S16 | cubic | I43d | a=14.2766 | band gap 1.87 eV | [59] | ||
[1,4-dabH2][Ag2SnS4] 1,4-dab = 1,4-diaminobutane | tetragonal | P42/n | a = 14.7847, c = 11.9087, Z = 8 | 2603.1 | [5][68] | ||
[H2en][Ag2SnS4] | [5] | ||||||
[CH3NH3]2Ag4SnIV2SnIIS8 | orthorhombic | Pnma | a =19.378 b =7.390 c =13.683 Z=4 | 1959 | 3.756 | Orange Sn(II) | [69] |
[CH3NH3]6Ag12Sn6S21 | monoclinic | P21/c | a =18.8646 b =19.9115 c =14.3125 β 100.117° | [70] | |||
[(Me)2NH2]3[Ag5Sn4Se12] | tetragonal | P421m | a=13.998 c=8.685 Z=2 | 1701.9 | 4.403 | dark red | [71] |
[enH][Cu2AgSnS4] | [5] | ||||||
Cu2CdSnS4 | I42m | a=5.402 c=10.86 Z=2 | 338 | 4.77 | [13] | ||
Ag2CdSnS4 | Cmc21 | a=4.111 b=7.038 c=6.685 Z=1 | 193 | 4.95 | [13] | ||
Cu2(Cd,Zn,Fe)SnS4 Černýite | tetragonal | I42m | a = 5.48, c = 10.828 Z=4 | 326 | 4.76 | metallic | [72] |
CuInSnS4 | a=10.50 Z=8 | 1158 | 4.91 | [13] | |||
AgInSnS4 | a=10.16 Z=8 | 1048 | 4.59 | [13] | |||
(Cu,Fe,Zn,Ag)3(Sn,In)S4 Petrukite | orthorhombic | a = 7.66, b = 6.43, c = 6.26 | 308 | brown | [73] | ||
(Cu,Zn,Fe)3(In,Sn)S4 Sakuraiite | isometric | a = 5.46 Z=1 | 162 | greenish grey | [74] | ||
Sn2S3 | orthorhombic | Pnma | a=8.864 b=3.7471 c=14.020 Z=4 | 466 | 4.76 | [13] | |
Cs4SnS4 | 0d | [3] | |||||
Cs2Sn3S7 ·0.5S8 | 2d | [3] | |||||
Cs4Sn5S12·2H2O | 2d | [3] | |||||
[Cs4(H2O)3][SnS4] | [15] | ||||||
Cs2Sn(S4)2(S6) | [3] | ||||||
Cs8Sn10O4S20·13H2O | [3] | ||||||
[Cs10(H2O)18][Mn4(μ4-S)(SnS4)4] | [15] | ||||||
Cs2ZnSn3S8 | monoclinic | P21/n | a 7.5366 b 17.6947 c 12.4976, β=94.830° Z=4 | 1660.7 | 3.775 | layered, band gap 3. eV | [55] |
[Ba2(H2O)11][SnS4] | [15] | ||||||
Li2Ba6MnSn4S16 | cubic | I43d | a=14.6080 Z=4 | 3117.3 | 4.007 | light yellow | [42] |
Ag2Ba6MnSn4S16 | cubic | I43d | a=14.7064 Z=4 | 3180.7 | 4.349 | yellow | [42] |
Ag2BaSnS4 | orthorhombic | I222 | a =7.127 b =8.117 c =6.854 Z=2 | black | [75] | ||
Ba3Ag2Sn2S8 | [76] | ||||||
BaSnS2 | Sn(II) | [77] | |||||
BaSn2S3 | Sn(II) | [77] | |||||
BaSnS3 | orthorhombic | Pnma | a=8.527 b=3.933 c=14.515 Z=4 | 487 | 4.8 | [13] | |
BaSnS3 | monoclinic | C2/c Cc | a=24.49 b=6.354 c=23.09 β=90.15 Z=28 | 3593 | 4.55 | [13] | |
α-Ba2SnS4 | monoclinic | P21/c | a=8.481 b=8.526 c=12.280 β=112.97 Z=4 | 818 | 4.24 | [13] | |
β-Ba2SnS4 | orthorhombic | Pnma | a=17.823 b=7.359 c=12.613 | 1654 | 4.18 | [13] | |
Ba3Sn2S7 | monoclinic | P21/c | a=11.073 b=6.771 c=18.703 β=100.77 Z=4 | 1378 | 4.21 | [13] | |
K2BaSnS4 | R3c | a 25.419 c 7.497 | band gap 3.09 eV; SHG 0.5×AgGaS2 | [78] | |||
Ba6Cu2FeSn4S16 | cubic | I43d | a=14.5260 | band gap 1.2 eV | [59] | ||
Ba6Cu2NiSn4S16 | cubic | I43d | a=14.511 | band gap 0.82 eV | [59] | ||
Ba6Li2ZnSn4S16 | cubic | I43d | a=14.5924 | [79] | |||
Ba6Ag2ZnSn4S16 | cubic | I43d | a=14.6839 | [79] | |||
BaCdSnS4 | orthorhombic | Fdd2 | a=21.57 b=21.76 c=13.110 Z=32 | 6152 | 4.290 | yellow | [80] |
Ba3CdSn2S8 | cubic | I43d | a=14.723 | [81] | |||
Ba6CdAg2Sn4S16 | cubic | I43d | a=14.725 | [81] | |||
La2SnS5 | orthorhombic | Pbam | a=11.22 b=7.915 c=3.97 Z=2 | 352 | 5.26 | [13] | |
[La(dien)3]2[Sn2S6]Cl2 | band gap 3.25 eV | [82] | |||||
La(peha)(μ–SnS4H) peha=pentaethylenehexamine | triclinic | P1 | a 8.609 b 9.327 c 14.649, α 79.2° β 85.5° γ 63.74° | [83] | |||
BaCeSn2S6 | orthorhombic | Pmc21 | a 4.0665 b 19.859 c 11.873 | [84] | |||
BaPrSn2S6 | orthorhombic | Pmc21 | a 4.0478 b 19.8914 c 11.9303 | [84] | |||
BaNdSn2S6 | orthorhombic | Pmc21 | a 4.0098 b 19.761 c 11.841 | [84] | |||
[Nd2(en)6(μ2-OH)2]Sn2S6 | monoclinic | P21/n | a =10.176, b =11.387, c=15.018, β =97.869° | [85] | |||
Nd(peha)(μ–SnS4H) | triclinic | P1 | a 8.621 b 9.372 c 14.656, α 78.28° β 84.33° γ 63.32° | [83] | |||
{Nd(tepa)(μ–OH)}2(μ–Sn2S6)]·H2O tepa=tetraethylenepentamine | monoclinic | C2/c | a=21.537 b=12.863 c=17.697 β=124.308° | [83] | |||
[Nd(dien)3]2[(Sn2S6)Cl2] dien = diethylenetriamine | monoclinic | P21/n | a = 11.672, b = 15.119, c = 14.157, β = 96.213°, Z = 4 | 2483.6 | [86] | ||
[Nd(dien)3]2[(Sn2S6)(SH)2] | monoclinic | P21/n | a = 11.719, b = 15.217, c = 14.221, β = 95.775°, Z = 4 | 2523.1 | [86] | ||
(tetaH)2[Eu2(teta)2(tren)2(μ-Sn2S6)]Sn2S6 | triclinic | P1 | a=9.886 b=10.371 c=17.442 α=89.78 β=88.00 γ=85.14 Z=1 | 1780.8 | 1.898 | light yellow | [60] |
[Eu2(tepa)2(μ-OH)2(μ-Sn2S6)](tepa)0.5·H2O tepa = tetraethylene-pentamine | monoclinic | C2/c | a=19.803 b=14.998 c=17.800 β=126.57 Z=4 | 4246 | 1.970 | colourless | [60] |
[{Eu(en)3}2(μ-OH)2]Sn2S6 | monoclinic | P21/n | a = 10.116, b = 11.379, c = 14.949, β = 98.209°, Z=2 | 1703.1 | [87] | ||
[{Eu(en)3}2(μ-OH)2]Sn2Se6 | monoclinic | P21/n | a = 10.136, b = 11.771, c = 15.423, β = 99.322°, Z = 2 | 1815.8 | [87] | ||
[Eu(dien)3]2[(Sn2S6)(SH)2] | monoclinic | P21/n | a = 11.656, b = 15.168, c = 14.173, β = 95.682°, Z = 2 | 2493.4 | [87] | ||
(tetaH)2[Sm2(teta)2(tren)2(μ-Sn2S6)]Sn2S6 | triclinic | P1 | a=9.920 b=10.382 c=17.520 α=89.91 β=88.07 γ=85.23 Z=1 | 1797.1 | 1.877 | light yellow | [60] |
{Sm(tepa)(μ–OH)}2(μ–Sn2S6)]·H2O | monoclinic | C2/c | a 21.487 b 12.8199 c 17.716 β 124.675° | [83] | |||
[Sm2(en)6(μ 2-OH)2]Sn2S6 | monoclinic | P21/n | a 10.129 b 11.377 c 14.962, β 98.128° | [88] | |||
[Sm(dien)3]2[(Sn2S6)Cl2] | monoclinic | P21/n | a 11.631 b 15.091 c 14.1420 β 96.202° | [88] | |||
[Sm(dien)3]2[(Sn2S6)(SH)2] | monoclinic | P21/n | a 11.698 b 15.212 c 14.219, β 95.654° | [88] | |||
[Sm(trien)(tren)(Cl)]2Sn2S6 · en | triclinic | P1 | a 10.320 b 10.491 c 13.791, α 100.524° β 91.930° γ 119.083° | [88] | |||
{Gd(tepa)(μ–OH)}2(μ–Sn2S6)]·H2O | monoclinic | C2/c | a 21.455 b 12.804 c 17.735 β 124.81° | [83] | |||
[Gd2(en)6(μ2-OH)2]Sn2S6 | monoclinic | P21/n | a =10.1053 b =11.357 c =14.924, β = 98.346° | [85] | |||
[Gd(dien)3]2[(Sn2S6)Cl2] dien = diethylenetriamine | monoclinic | P21/n | a =11.662, b =15.168. c 14.185, β =95.696° | [85] | |||
{Dy(tepa)(μ–OH)}2(μ–Sn2S6)]·H2O | monoclinic | C2/c | a 21.363 b 12.717 c 17.654 β 124.915° | [83] | |||
[Hen]2[La(en)4(CuSn3S9)]⋅0.5 en | [89] | ||||||
[Hen]2[Ce(en)4(CuSn3S9)]⋅0.5 en | [89] | ||||||
[Hen]4[Nd(en)4]2[Cu6Sn6S20]⋅3 en | [89] | ||||||
[enH]4[Sm(en)4]2[Cu6Sn6S20]·3en | monoclinic | C2/m | a 14.257 b 24.242 c 13.119 β 92.223° | [90] | |||
[Hen]4[Gd(en)4]2[Cu6Sn6S20]⋅3 en | [89] | ||||||
[enH]4[Ho(en)4]2[Cu6Sn6S20]·3en | monoclinic | C2/m | a 14.3859 b 24.361 c 13.175, β 93.526° | [90] | |||
EuCu2SnS4 | orthorhombic | Ama2 | a=10.4793, b=10.3610, c=6.4015, Z=4 | [91][92] | |||
[Hen]4[Er(en)4]2[Cu6Sn6S20]⋅3 en | [89] | ||||||
[Hen]4[Er(en)4]2[Ag6Sn6S20]·3en | monoclinic | C2/m | a 14.557 b 24.397 c 13.412 β 94.42° | [93] | |||
[Hen]4[Tm(en)4]2[Ag6Sn6S20]·3en | monoclinic | C2/m | a 14.517 b 24.380 c 13.422 β 94.46° | [93] | |||
[Hen]4[Yb(en)4]2[Ag6Sn6S20]·3en | monoclinic | C2/m | a 14.536 b 24.397 c 13.397, β 94.63° | [93] | |||
Cu6SnWS8 Kiddcreekite | isometric | F43m | a = 10.8178 Z=4 | 1265.9 | 4.934 | grey | [94] |
PtSnS Bowlesite | orthorhombic | Pca21 | a = 6.12 Å, b = 6.12 Å, c = 6.10 Å Z=4 | 228.47 | 10.06 | metallic | [95] |
(Pd,Pt)5(Cu,Fe)4SnTe2S2 Oulankaite | tetragonal | a = 9.044, c = 4.937 Z=2 | 403.8 | 10.27 | metallic | ||
K2Au2SnS4 | triclinic | P1 | a=8.212 b=11.019 c=7.314 α=97.82° β=111.72° γ=72.00° Z=2 | 483.2 | 4.941 | band gap 2.75 eV | [96][54] |
K2Au2Sn2S6 | tetragonal | P4/mmc | a=7.968 c=19.200 Z=4 | 1219 | 4.914 | band gap 2.30 eV | [96][54] |
Cs2Au2SnS4 | orthorhombic | Fddd | a = 6.143 b = 14.296 c = 24.578 Z = 4 | 2158.4 | [96] | ||
Ba[Au2SnS4] | orthorhombic | C2221 | a=6.6387 b=11.0605 c=10.9676 Z=1 | 805.32 | 6.418 | red; blue-green luminescent | [96] |
K2Hg3Sn2S8 | [97] | ||||||
Cu2HgSnS4 Velikite | tetrahedral | I42m | a = 5.55, c = 10.91 | 336 | 5.450 | dark grey | [98] |
SrHgSnSe4 | [99] | ||||||
BaHgSnSe4 | orthorhombic | Fdd2 | a 22.441 b 22.760 c 13.579 | [99] | |||
EuHgSnS4 | Ama2 | a=10.3730 b=10.4380 c=6.5680 | SHG 1.77×AgGaS2 | [100] | |||
Tl4SnS4 | 0d | ||||||
Tl2SnS3 | 1d | ||||||
Tl2Sn2S5 | 3d | ||||||
Tl4Sn5S12 | 3d | ||||||
PbSnS2 Teallite | orthorhombic | Pnma | a = 4.26, b = 11.41, c = 4.09 | 198.8 | 6.36 | metallic | |
PbSnS3 Suredaite | orthorhombic | Pnma | a=8.738 b=3.792 c=14.052 Z=4 | 466 | 6.01 | metallic | [13] |
(Pb,Sn)12.5Sn5FeAs3S28 Coiraite | monoclinic | a = 5.84, b = 5.86, c = 17.32 β = 94.14° Z=4 | 591 | 5.92 | dark grey | [101] | |
Fe2+(Pb,Sn2+)6Sn4+2Sb2S14 Franckeite | triclinic | P1 | a = 46.9, b = 5.82, c = 17.3 α = 90°, β = 94.66°, γ = 90° Z=8 | 4701 | 5.90 | black | [102] |
Pb25.7Sn8.3Mn3.4Sb6.4S56.2 Ramosite | monoclinic | a = 5.82, b = 5.92, c = 17.65 β = 99.1° | 600 | [103] | |||
Pb3Sn4FeSb2S14 Cylindrite | triclinic | P1 | 5.46 | black | [104] | ||
Pb6Sn3FeSb3S16 Potosíite | triclinic | grey | |||||
(Pb,Ag)4Sn4FeSb2S15 Incaite | monoclinic | [105] | |||||
Pb2Fe2Sn2Sb2S11 Plumbostannite | dark grey | [106] | |||||
Ba5Pb2Sn3S13 | orthorhombic | Pnma | [107] | ||||
Pb2SnInBiS7 Abramovite | triclinic | P1 | a = 23.4, b = 5.77, c = 5.83 α = 89.1°, β = 89.9°, γ = 91.5° | 786.79 | metallic | [108] | |
Pb8Sn7Cu3(Bi,Sb)3S28 Lévyclaudite | triclinic | P1 | 5.71 | grey | [109] |
References
- ^ Benkada, Assma; Reinsch, Helge; Poschmann, Michael; Krahmer, Jan; Pienack, Nicole; Bensch, Wolfgang (18 February 2019). "Synthesis and Characterization of a Rare Transition-Metal Oxothiostannate and Investigation of Its Photocatalytic Properties". Inorganic Chemistry. 58 (4): 2354–2362. doi:10.1021/acs.inorgchem.8b02773. PMID 30702285. S2CID 73413851.
- ^ a b c Lühmann, Henning; Näther, Christian; Jess, Inke; Bensch, Wolfgang (2019-10-14). "Synthesis, Crystal Structure, and Thermal Properties of Na 5 [SnS 4 ]Cl·13H 2 O". Zeitschrift für anorganische und allgemeine Chemie. 645 (18–19): 1165–1170. doi:10.1002/zaac.201900169. ISSN 0044-2313.
- ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac Sheldrick, William S.; Wachhold, Michael (September 1998). "Chalcogenidometalates of the heavier Group 14 and 15 elements". Coordination Chemistry Reviews. 176 (1): 211–322. doi:10.1016/s0010-8545(98)00120-9.
- ^ a b c d e Hilbert, Jessica; Näther, Christian; Bensch, Wolfgang (2017-12-13). "Fast Room Temperature Synthesis of the Thiostannate [Ni(2amp) 3 ] 2 [Sn 2 S 6 ]·9.5H 2 O: Crystal Structure and Properties: Fast Room Temperature Synthesis of the Thiostannate [Ni(2amp) 3 ] 2 [Sn 2 S 6 ]·9.5H 2 O: Crystal Structure and Properties". Zeitschrift für anorganische und allgemeine Chemie. 643 (23): 1861–1866. doi:10.1002/zaac.201700193.
- ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah Benkada, Assma; Reinsch, Helge; Bensch, Wolfgang (2019-11-10). "The First Thiostannate Compound with Copper(II) Synthesized Under Ambient Conditions: Crystal Structure, Electronic and Thermal Properties". European Journal of Inorganic Chemistry. 2019 (41): 4427–4432. doi:10.1002/ejic.201900924. ISSN 1434-1948.
- ^ Kaib, Thomas; Haddadpour, Sima; Kapitein, Manuel; Bron, Philipp; Schröder, Cornelia; Eckert, Hellmut; Roling, Bernhard; Dehnen, Stefanie (2012-06-12). "New Lithium Chalcogenidotetrelates, LiChT: Synthesis and Characterization of the Li + -Conducting Tetralithium ortho- Sulfidostannate Li 4 SnS 4". Chemistry of Materials. 24 (11): 2211–2219. doi:10.1021/cm3011315. ISSN 0897-4756.
- ^ Kaib, Thomas; Kapitein, Manuel; Dehnen, Stefanie (October 2011). "Synthesis and Crystal Structure of [Li8(H2O)29][Sn10O4S20]·2H2O". Zeitschrift für anorganische und allgemeine Chemie. 637 (12): 1683–1686. doi:10.1002/zaac.201100268.
- ^ a b Nørby, Peter; Overgaard, Jacob; Christensen, Per S.; Richter, Bo; Song, Xin; Dong, Mingdong; Han, Anpan; Skibsted, Jørgen; Iversen, Bo B.; Johnsen, Simon (2014-08-12). "(NH 4 ) 4 Sn 2 S 6 ·3H 2 O: Crystal Structure, Thermal Decomposition, and Precursor for Textured Thin Film". Chemistry of Materials. 26 (15): 4494–4504. doi:10.1021/cm501681r. ISSN 0897-4756.
- ^ a b c Nørby, Peter; Eikeland, Espen; Overgaard, Jacob; Johnsen, Simon; Iversen, Bo B. (2015). "Expanding the structural versatility of thiostannate( iv ) complexes". CrystEngComm. 17 (11): 2413–2420. doi:10.1039/C4CE02224F. ISSN 1466-8033.
- ^ a b Pienack, Nicole; Näther, Christian; Bensch, Wolfgang (March 2009). "Solvothermal Syntheses of Two New Thiostannates and an In-Situ Energy Dispersive X-ray Scattering Study of Their Formation". European Journal of Inorganic Chemistry. 2009 (7): 937–946. doi:10.1002/ejic.200801084.
- ^ Filsø, Mette Ø.; Chaaban, Iman; Al Shehabi, Amer; Skibsted, Jørgen; Lock, Nina (2017-10-01). "The structure-directing amine changes everything: structures and optical properties of two-dimensional thiostannates". Acta Crystallographica Section B. 73 (5): 931–940. Bibcode:2017AcCrB..73..931F. doi:10.1107/S2052520617010630. ISSN 2052-5206. PMID 28980999.
- ^ a b Pada Nayek, Hari; Lin, Zhien; Dehnen, Stefanie (October 2009). "Solvent-modified SiS 2 -type SnS 2: Synthesis, Crystal Structures and Properties of {}^1_\infty[SnS 2 · en ] and [ en H] 4 [Sn 2 S 6 ]· en". Zeitschrift für anorganische und allgemeine Chemie. 635 (12): 1737–1740. doi:10.1002/zaac.200900157.
- ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah ai aj Olivier-Fourcade, J.; Jumas, J.C.; Ribes, M.; Philippot, E.; Maurin, M. (January 1978). "Evolution structurale et nature des liaisons dans la série des composés soufrés du silicium, du germanium, et de l'étain". Journal of Solid State Chemistry (in French). 23 (1–2): 155–176. Bibcode:1978JSSCh..23..155O. doi:10.1016/0022-4596(78)90062-2.
- ^ Heppke, Eva M.; Lerch, Martin (2020-09-25). "Na 2 MgSnS 4 – a new member of the A 2 I B II C IV X 4 family of compounds". Zeitschrift für Naturforschung B. 75 (8): 721–726. doi:10.1515/znb-2020-0102. ISSN 1865-7117. S2CID 222005297.
- ^ a b c d e Ruzin, Eugen; Jakobi, Stephan; Dehnen, Stefanie (June 2008). "Syntheses, Structures and Reactivity of Novel Hydrates ofortho-Sulfidostannte Salts". Zeitschrift für anorganische und allgemeine Chemie (in German). 634 (6–7): 995–1001. doi:10.1002/zaac.200800004.
- ^ a b c d e Chen, Yao; Liu, Xing; Zhou, Jian; Zou, Hua-hong; Xiang, Bin (2021-02-15). "One-Dimensional Vanadium(III) Chalcogenidostannates Incorporating [V(tepa)] 3+ Complexes as Bridging Groups". Inorganic Chemistry. 60 (4): 2127–2132. doi:10.1021/acs.inorgchem.0c03484. ISSN 0020-1669. PMID 33503370. S2CID 231765552.
- ^ a b c Jia, Ding-Xian; Zhang, Yong; Dai, Jie; Zhu, Qin-Yu; Gu, Xiao-Mei (February 2004). "Solvothermal Syntheses and Characterization of Thiostannates [M(en)3]2Sn2S6 (M = Mn, Co, Zn), the Influence of Metal Ions on the Crystal Structure". Zeitschrift für anorganische und allgemeine Chemie. 630 (2): 313–318. doi:10.1002/zaac.200300327. ISSN 0044-2313.
- ^ a b Fu, M. L.; Guo, G. C.; Liu, B.; Wu, A. Q.; Huang, J. S. (2005). "Two new thiostannates templated by transition metal complexes". Chinese Journal of Inorganic Chemistry. 21 (1): 25–29.
- ^ a b c Han, Jing-yu; Liu, Yun; Lu, Jia-lin; Tang, Chun-ying; Shen, Ya-li; Zhang, Yong; Jia, Ding-xian (July 2015). "Methanolothermal Syntheses, Crystal Structures and Optical Properties of Binuclear Transition Metal Complexes Involving the Bidentate S-Donor Ligand μ-Sn2S6". Journal of Chemical Crystallography. 45 (7): 355–362. doi:10.1007/s10870-015-0601-3. ISSN 1074-1542. S2CID 93060529.
- ^ Han, Jingyu; Li, Shufen; Zhang, Limei; Zheng, Wei; Jiang, Wenqing; Jia, Dingxian (July 2018). "T3 supertetrahedral cluster [Mn 4 Sn 6 S 20 ] 8−: Solvothermal syntheses, crystal structures and photocatalytic properties of Mn(II) chalcogenidostannates". Inorganic Chemistry Communications. 93: 73–77. doi:10.1016/j.inoche.2018.05.004. S2CID 104109618.
- ^ Pienack, Nicole; Näther, Christian; Bensch, Wolfgang (April 2009). "The Inorganic-Organic Hybrid Compound {[Mn(trien)] 2 SnS 4 }·4H 2 O: Exhibiting a Hitherto Unknown Binding Mode of the [SnS 4 ] 4- Tetrahedron". European Journal of Inorganic Chemistry. 2009 (12): 1575–1577. doi:10.1002/ejic.200801093.
- ^ a b c d Hilbert, Jessica; Näther, Christian; Bensch, Wolfgang (2014-06-02). "Influence of the Synthesis Parameters onto Nucleation and Crystallization of Five New Tin–Sulfur Containing Compounds". Inorganic Chemistry. 53 (11): 5619–5630. doi:10.1021/ic500369m. ISSN 0020-1669. PMID 24845345.
- ^ Liu, Guang-Ning; Guo, Guo-Cong; Chen, Feng; Guo, Sheng-Ping; Jiang, Xiao-Ming; Yang, Chen; Wang, Ming-Sheng; Wu, Mei-Feng; Huang, Jin-Shun (2010). "Stabilization of (SnS4)4− anion by coordinating to [TM(π-conjugated-ligand)m]n+ complex: a chain-like thiostannate(iv) {[Mn(phen)]2(SnS4)}n·nH2O exhibiting an unprecedented link mode of the (SnS4)4− anion". CrystEngComm. 12 (12): 4035. doi:10.1039/c0ce00292e. ISSN 1466-8033.
- ^ a b Hilbert, Jessica; Pienack, Nicole; Lühmann, Henning; Näther, Christian; Bensch, Wolfgang (December 2016). "Transition Metal Complexes with Linkage to the Thiostannate Units Forced by Suitable Amine Molecules: Transition Metal Complexes with Linkage to the Thiostannate Units Forced by Suitable Amine Molecules". Zeitschrift für anorganische und allgemeine Chemie. 642 (24): 1427–1434. doi:10.1002/zaac.201600318.
- ^ Pienack, Nicole; Möller, Karina; Näther, Christian; Bensch, Wolfgang (December 2007). "(1,4-dabH)2MnSnS4: The first thiostannate with integrated Mn2+ ions in an anionic chain structure". Solid State Sciences. 9 (12): 1110–1114. Bibcode:2007SSSci...9.1110P. doi:10.1016/j.solidstatesciences.2007.07.030.
- ^ Kaib, Thomas; Haddadpour, Sima; Andersen, Hanne Flåten; Mayrhofer, Leonhard; Järvi, Tommi T.; Moseler, Michael; Möller, Kai-Christian; Dehnen, Stefanie (10 December 2013). "Quaternary Diamond-Like Chalcogenidometalate Networks as Efficient Anode Material in Lithium-Ion Batteries". Advanced Functional Materials. 23 (46): 5693–5699. doi:10.1002/adfm.201301025. S2CID 93236286.
- ^ a b c Pienack, Nicole; Lehmann, Stefanie; Lühmann, Henning; El-Madani, Marzog; Näther, Christian; Bensch, Wolfgang (October 2008). "Solvothermal Syntheses, Crystal Structures and Selected Optical Properties of [ M (C 8 N 5 H 23 )] 2 Sn 2 S 6 ( M = Co, Fe, Ni; C 8 N 5 H 23 = tetraethylenepentamine)". Zeitschrift für anorganische und allgemeine Chemie. 634 (12–13): 2323–2329. doi:10.1002/zaac.200800282.
- ^ Zeisler, Christoph; Näther, Christian; Bensch, Wolfgang (2013). "A new synthetic approach to force bond formation between a transition metal complex and a thiostannate anion: solvothermal synthesis and crystal structure of [Co2(cyclam)2Sn2S6]·2H2O". CrystEngComm. 15 (44): 8874. doi:10.1039/c3ce40976g. ISSN 1466-8033.
- ^ a b Lühmann, Henning; Jeß, Inke; Näther, Christian; Bensch, Wolfgang (2020-02-28). "Crystal Structures and Selected Properties of Co II Containing Thiostannates prepared by a New Room Temperature Route". Zeitschrift für anorganische und allgemeine Chemie. 646 (4): 234–240. doi:10.1002/zaac.201900227. ISSN 0044-2313.
- ^ "Butianite". www.mindat.org. Retrieved 2021-07-08.
- ^ a b Benkada, Assma (2020-11-30). Synthesis of Thiostannates, Oxo-Thiostannates and Tin-Sulfides Applying Transition Metal Complexes Containing Macrocyclic Amine Molecules: Development of new synthetic routes to synthesize Sn-S and S-Sn-O compounds and investigation of their properties (Thesis).
- ^ Benkada, Assma; Poschmann, Michael; Näther, Christian; Bensch, Wolfgang (2019-02-28). "New Transition Metal Oxo-Thiostannate: Synthesis, Characterization, and Investigation of its Photocatalytic Properties: New Transition Metal Oxo-Thiostannate: Synthesis, Characterization, and Investigation of its Photocatalytic Properties". Zeitschrift für anorganische und allgemeine Chemie. 645 (4): 433–439. doi:10.1002/zaac.201800475. S2CID 104376198.
- ^ a b c Hilbert, Jessica; Näther, Christian; Weihrich, Richard; Bensch, Wolfgang (2016-08-15). "Room-Temperature Synthesis of Thiostannates from {[Ni(tren)] 2 [Sn 2 S 6 ]} n". Inorganic Chemistry. 55 (16): 7859–7865. doi:10.1021/acs.inorgchem.6b00625. ISSN 0020-1669. PMID 27479453.
- ^ a b Hilbert, Jessica; Näther, Christian; Bensch, Wolfgang (April 2017). "Studies of the reactivity of {[Ni(tren)]2[Sn2S6]}: Synthesis and crystal structures of two new thiostannates prepared at room temperature". Inorganica Chimica Acta. 459: 29–35. doi:10.1016/j.ica.2017.01.018.
- ^ a b c d e f Hilbert, Jessica; Näther, Christian; Bensch, Wolfgang (2017-09-06). "Applying Ni(II) Amine Complexes and Sodium Thiostannate as Educts for the Generation of Thiostannates at Room Temperature". Crystal Growth & Design. 17 (9): 4766–4775. doi:10.1021/acs.cgd.7b00728. ISSN 1528-7483.
- ^ a b Hilbert, J.; Näther, C.; Bensch, W. (2015). "Utilization of mixtures of aromatic N-donor ligands of different coordination ability for the solvothermal synthesis of thiostannate containing molecules". Dalton Transactions. 44 (25): 11542–11550. doi:10.1039/C5DT01145K. ISSN 1477-9226. PMID 26031892.
- ^ a b Benkada, Assma; Näther, Christian; Bensch, Wolfgang (2020-08-31). "Room Temperature Synthesis of New Thiostannates by Slow Interdiffusion of Different Solvents". Zeitschrift für anorganische und allgemeine Chemie. 646 (16): 1352–1358. doi:10.1002/zaac.202000199. ISSN 0044-2313.
- ^ "Mohite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Kuramite Mineral Data". webmineral.com. Retrieved 2021-07-08.
- ^ Chen, X.-a; Wada, H; Sato, A (January 1999). "Preparation, crystal structure and electrical properties of Cu4SnS6". Materials Research Bulletin. 34 (2): 239–247. doi:10.1016/S0025-5408(99)00013-6.
- ^ Pienack, Nicole; Näther, Christian; Bensch, Wolfgang (January 2007). "Two new copper thiostannates synthesised under solvothermal conditions: Crystal structures, spectroscopic and thermal properties of (DBUH)CuSnS3 and (1,4-dabH2)Cu2SnS4". Solid State Sciences. 9 (1): 100–107. Bibcode:2007SSSci...9..100P. doi:10.1016/j.solidstatesciences.2006.11.012.
- ^ a b c Duan, Ruihuan; Lin, Hua; Wang, Yue; Zhou, Yuqiao; Wu, Liming (2020). "Non-centrosymmetric sulfides A 2 Ba 6 MnSn 4 S 16 (A = Li, Ag): syntheses, structures and properties". Dalton Transactions. 49 (18): 5914–5920. doi:10.1039/D0DT00894J. ISSN 1477-9226. PMID 32314776. S2CID 216046852.
- ^ a b c Behrens, Malte; Ordolff, Marie-Eve; Näther, Christian; Bensch, Wolfgang; Becker, Klaus-Dieter; Guillot-Deudon, Catherine; Lafond, Alain; Cody, Jason A. (2010-09-20). "New Three-Dimensional Thiostannates Composed of Linked Cu 8 S 12 Clusters and the First Example of a Mixed-Metal Cu 7 SnS 12 Cluster". Inorganic Chemistry. 49 (18): 8305–8309. doi:10.1021/ic100688z. ISSN 0020-1669. PMID 20726515.
- ^ a b Lühmann, Henning; Jeß, Inke; Näther, Christian; Bensch, Wolfgang (2020-02-28). "Crystal Structures and Selected Properties of Co II Containing Thiostannates prepared by a New Room Temperature Route". Zeitschrift für anorganische und allgemeine Chemie. 646 (4): 234–240. doi:10.1002/zaac.201900227. ISSN 0044-2313. S2CID 214133328.
- ^ a b Zhang, Xian; Wang, Qiuran; Ma, Zhimin; He, Jianqiao; Wang, Zhe; Zheng, Chong; Lin, Jianhua; Huang, Fuqiang (2015-06-01). "Synthesis, Structure, Multiband Optical, and Electrical Conductive Properties of a 3D Open Cubic Framework Based on [Cu 8 Sn 6 S 24 ] z − Clusters". Inorganic Chemistry. 54 (11): 5301–5308. doi:10.1021/acs.inorgchem.5b00317. ISSN 0020-1669. PMID 25955506.
- ^ "Stannite". www.mindat.org. Retrieved 2021-07-08.
- ^ "Mawsonite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Chatkalite". www.mindat.org. Retrieved 2021-07-08.
- ^ "Nekrasovite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Search Results – Access Structures". www.ccdc.cam.ac.uk. Retrieved 2021-07-14.
- ^ "Kësterite". www.mindat.org. Retrieved 2021-07-08.
- ^ "Stannoidite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Ge-Sn-Sulvanite". www.mindat.org. Retrieved 2021-07-15.
- ^ a b c d Liao, Ju Hsiou; Kanatzidis, Mercouri G. (1993-10-01). "Quaternary rubidium copper tin sulfides (Rb2Cu2SnS4, A2Cu2Sn2S6 (A = Na, K, Rb, Cs), A2Cu2Sn2Se6 (A = K, Rb), potassium gold tin sulfides, K2Au2SnS4, and K2Au2Sn2S6. Syntheses, structures, and properties of new solid-state chalcogenides based on tetrahedral [SnS4]4- units". Chemistry of Materials. 5 (10): 1561–1569. doi:10.1021/cm00034a029. ISSN 0897-4756.
- ^ a b Tian, Tian; Li, Zefen; Wang, Naizheng; Zhao, Sangen; Xu, Jiayue; Lin, Zheshuai; Mei, Dajiang (2021-06-16). "Cs 2 ZnSn 3 S 8: A Sulfide Compound Realizes a Large Birefringence by Modulating the Dimensional Structure". Inorganic Chemistry. 60 (13): 9248–9253. doi:10.1021/acs.inorgchem.1c01024. PMID 34132527. S2CID 235450479.
- ^ Liu, Chuang; Mei, Dajiang; Cao, Wangzhu; Yang, Yi; Wu, Yuandong; Li, Guobao; Lin, Zheshuai (2019). "Mn-Based tin sulfide Sr 3 MnSn 2 S 8 with a wide band gap and strong nonlinear optical response". Journal of Materials Chemistry C. 7 (5): 1146–1150. doi:10.1039/C8TC05904G. ISSN 2050-7526. S2CID 139249564.
- ^ Teske, Chr. L. (January 1976). "Darstellung und Kristallstruktur von Cu2SrSnS4". Zeitschrift für anorganische und allgemeine Chemie (in German). 419 (1): 67–76. doi:10.1002/zaac.19764190112. ISSN 0044-2313.
- ^ a b Yang, Ya; Song, Miao; Zhang, Jie; Gao, Lihua; Wu, Xiaowen; Wu, Kui (2020). "Coordinated regulation on critical physiochemical performances activated from mixed tetrahedral anionic ligands in new series of Sr 6 A 4 M 4 S 16 (A = Ag, Cu; M = Ge, Sn) nonlinear optical materials". Dalton Transactions. 49 (11): 3388–3392. doi:10.1039/D0DT00432D. ISSN 1477-9226. PMID 32104856. S2CID 211535947.
- ^ a b c d Zhang, Lingyun; Mei, Dajiang; Wu, Yuanwang; Shen, Chenfei; Hu, Wenxin; Zhang, Lujia; Li, Jinjin; Wu, Yuandong; He, Xiao (April 2019). "Syntheses, structures, optical properties, and electronic structures of Ba6Cu2GSn4S16 (G = Fe, Ni) and Sr6D2FeSn4S16 (D = Cu, Ag)". Journal of Solid State Chemistry. 272: 69–77. Bibcode:2019JSSCh.272...69Z. doi:10.1016/j.jssc.2019.01.024. S2CID 104331229.
- ^ a b c d Zhou, Jian; Liu, Xing; An, Litao; Hu, Feilong; Yan, Wenbin; Zhang, Yunyan (2012-02-20). "Solvothermal Synthesis and Characterization of a Series of Lanthanide Thiostannates(IV): The First Examples of Inorganic–Organic Hybrid Cationic Lanthanide Thiostannates(IV)". Inorganic Chemistry. 51 (4): 2283–2290. doi:10.1021/ic2023083. ISSN 0020-1669. PMID 22280530.
- ^ "Canfieldite". www.mindat.org. Retrieved 2021-07-15.
- ^ Yang, Ya; Wu, Kui; Zhang, Bingbing; Wu, Xiaowen; Lee, Ming-Hsien (2020-02-17). "One-Dimensional Double Chains in Sodium-Based Quaternary Chalcogenides Displaying Intriguing Red Emission and Large Optical Anisotropy". Inorganic Chemistry. 59 (4): 2519–2526. doi:10.1021/acs.inorgchem.9b03444. ISSN 0020-1669. PMID 31999111. S2CID 210947790.
- ^ "Agmantinite". www.mindat.org. Retrieved 2021-07-08.
- ^ "Pirquitasite". www.mindat.org. Retrieved 2021-07-08.
- ^ "Hocartite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Toyohaite". www.mindat.org. Retrieved 2021-07-15.
- ^ Xiong, Wei-Wei; Miao, Jianwei; Li, Pei-Zhou; Zhao, Yanli; Liu, Bin; Zhang, Qichun (2014). "[enH][Cu 2 AgSnS 4 ]: a quaternary layered sulfide based on Cu–Ag–Sn–S composition". CrystEngComm. 16 (27): 5989–5992. doi:10.1039/C4CE00740A. ISSN 1466-8033.
- ^ Pienack, Nicole; Bensch, Wolfgang (August 2006). "The New Silver Thiostannate (1,4-dabH2)Ag2SnS4: Solvothermal Synthesis, Crystal Structure and Spectroscopic Properties". Zeitschrift für anorganische und allgemeine Chemie (in German). 632 (10–11): 1733–1736. doi:10.1002/zaac.200600111. ISSN 0044-2313.
- ^ Zhang, Bo; Li, Jun; Du, Cheng-Feng; Feng, Mei-Ling; Huang, Xiao-Ying (2016-11-07). "[CH 3 NH 3 ] 2 Ag 4 Sn IV 2 Sn II S 8: An Open-Framework Mixed-Valent Chalcogenidostannate". Inorganic Chemistry. 55 (21): 10855–10858. doi:10.1021/acs.inorgchem.6b02317. ISSN 0020-1669. PMID 27768295.
- ^ Zhang, Bo; Feng, Mei-Ling; Li, Jun; Hu, Qian-Qian; Qi, Xing-Hui; Huang, Xiao-Ying (March 2017). "Syntheses, Crystal Structures, and Optical and Photocatalytic Properties of Four Small-Amine-Molecule-Directed M–Sn–Q (M = Zn, Ag; Q = S, Se) Compounds". Crystal Growth & Design. 17 (3): 1235–1244. doi:10.1021/acs.cgd.6b01619. ISSN 1528-7483.
- ^ Li, Jian-Rong; Huang, Xiao-Ying (2011). "[(Me)2NH2]0.75[Ag1.25SnSe3]: A three-dimensionally microporous chalcogenide exhibiting framework flexibility upon ion-exchange". Dalton Transactions. 40 (17): 4387–4390. doi:10.1039/c0dt01381a. ISSN 1477-9226. PMID 21225068.
- ^ "Černýite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Petrukite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Sakuraiite". www.mindat.org. Retrieved 2021-07-15.
- ^ Teske, Chr. L. (October 1978). "Darstellung und Kristallstruktur von Gold-Barium-Thiostannat(lV), Au2,BaSnS4". Zeitschrift für anorganische und allgemeine Chemie (in German). 445 (1): 193–201. doi:10.1002/zaac.19784450124. ISSN 0044-2313.
- ^ Liu, Yan; Li, Yanhua; Zhao, Jie; Zhang, Renchun; Ji, Min; You, Zhonglu; An, Yonglin (January 2020). "Solvothermal syntheses, characterizations and semiconducting properties of four quaternary thioargentates Ba2AgInS4, Ba3Ag2Sn2S8, BaAg2MS4 (M = Sn, Ge)". Journal of Alloys and Compounds. 815: 152413. doi:10.1016/j.jallcom.2019.152413. S2CID 204304414.
- ^ a b Sheldrick, William S.; Wachhold, Michael (September 1998). "Chalcogenidometalates of the heavier Group 14 and 15 elements". Coordination Chemistry Reviews. 176 (1): 211–322. doi:10.1016/S0010-8545(98)00120-9.
- ^ Luo, Xiaoyu; Li, Zhuang; Liang, Fei; Guo, Yangwu; Wu, Yicheng; Lin, Zheshuai; Yao, Jiyong (2019-05-20). "Synthesis, Structure, and Characterization of Two Mixed-Cation Quaternary Chalcogenides K 2 BaSnQ 4 (Q = S, Se)". Inorganic Chemistry. 58 (10): 7118–7125. doi:10.1021/acs.inorgchem.9b00967. ISSN 0020-1669. PMID 31067038. S2CID 148568495.
- ^ a b Duan, Rui-Huan; Li, Rui-An; Liu, Peng-Fei; Lin, Hua; Wang, Yue; Wu, Li-Ming (2018-09-05). "Modifying Disordered Sites with Rational Cations to Regulate Band-Gaps and Second Harmonic Generation Responses Markedly: Ba 6 Li 2 ZnSn 4 S 16 vs Ba 6 Ag 2 ZnSn 4 S 16 vs Ba 6 Li 2.67 Sn 4.33 S 16". Crystal Growth & Design. 18 (9): 5609–5616. doi:10.1021/acs.cgd.8b00927. ISSN 1528-7483. S2CID 105919832.
- ^ Zhen, Ni; Wu, Kui; Wang, Ying; Li, Qiang; Gao, Wenhui; Hou, Dianwei; Yang, Zhihua; Jiang, Huaidong; Dong, Yongjun; Pan, Shilie (2016). "BaCdSnS 4 and Ba 3 CdSn 2 S 8: syntheses, structures, and non-linear optical and photoluminescence properties". Dalton Transactions. 45 (26): 10681–10688. doi:10.1039/C6DT01537A. ISSN 1477-9226. PMID 27272926.
- ^ a b Teske, Chr. L. (1985). "Darstellung und Kristallstruktur von Ba3CdSn2S8 mit einer Anmerkung über Ba6CdAg2Sn4S16". Zeitschrift für anorganische und allgemeine Chemie (in German). 522 (3): 122–130. doi:10.1002/zaac.19855220315. ISSN 0044-2313.
- ^ Pienack, Nicole; Lühmann, Henning; Näther, Christian; Bensch, Wolfgang (January 2016). "A New Solvothermal Synthetic Route Yields the New Thiostannate [La(dien) 3 ] 2 [Sn 2 S 6 ]Cl 2: The New Thiostannate [La(dien) 3 ] 2 [Sn 2 S 6 ]Cl 2". Zeitschrift für anorganische und allgemeine Chemie. 642 (1): 25–30. doi:10.1002/zaac.201500661.
- ^ a b c d e f Tang, Chunying; Lu, Jialin; Han, Jingyu; Liu, Yun; Shen, Yali; Jia, Dingxian (October 2015). "Complexations of Ln(III) with SnS4H and Sn2S6: Solvothermal syntheses and characterizations of lanthanide coordination polymers with thiostannate and polyamine mixed ligands". Journal of Solid State Chemistry. 230: 118–125. Bibcode:2015JSSCh.230..118T. doi:10.1016/j.jssc.2015.06.008.
- ^ a b c Feng, Kai; Zhang, Xu; Yin, Wenlong; Shi, Youguo; Yao, Jiyong; Wu, Yicheng (2014-02-17). "New Quaternary Rare-Earth Chalcogenides Ba Ln Sn 2 Q 6 ( Ln = Ce, Pr, Nd, Q = S; Ln = Ce, Q = Se): Synthesis, Structure, and Magnetic Properties". Inorganic Chemistry. 53 (4): 2248–2253. doi:10.1021/ic402934m. ISSN 0020-1669. PMID 24498849.
- ^ a b c Zhao, Qianxin; Jia, Dingxian; Zhang, Yong; Song, Lifeng; Dai, Jie (April 2007). "First example of thiostannates with lanthanide-containing counter cations: Solvothermal synthesis, crystal structures and properties of thiostannates with neodymium(III) and gadolinium(III) complexes of bidentate and tridentate amino ligands". Inorganica Chimica Acta. 360 (6): 1895–1901. doi:10.1016/j.ica.2006.09.023.
- ^ a b Lu, Xin-hua; Liang, Jing-jing; Zhao, Jing; Zhang, Yong; Jia, Ding-xian (April 2011). "Solvothermal Syntheses and Crystal Structures of Neodymium Thiostannates [Nd(dien)3]2[(Sn2S6)Cl2] and [Nd(dien)3]2[(Sn2S6)(SH)2]". Journal of Chemical Crystallography. 41 (4): 557–562. doi:10.1007/s10870-010-9921-5. ISSN 1074-1542. S2CID 95550419.
- ^ a b c Chen, Rui-hong; Wang, Fang; Tang, Chun-ying; Zhang, Yong; Jia, Ding-xian (June 2013). "Solvothermal Syntheses and Crystal Structures of Hexachalcogenidodistannates with Europium Complexes of Different Ethylene Polyamine Ligands". Journal of Chemical Crystallography. 43 (6): 319–324. doi:10.1007/s10870-013-0423-0. ISSN 1074-1542. S2CID 97917911.
- ^ a b c d Jin, Qinyan; Chen, Jiangfang; Pan, Yingli; Zhang, Yong; Jia, Dingxian (2010-05-10). "Solvothermal syntheses and optical properties of hexathiostannates containing samarium(III) complexes with different ethylene polyamines". Journal of Coordination Chemistry. 63 (9): 1492–1503. doi:10.1080/00958972.2010.482666. ISSN 0095-8972. S2CID 98109293.
- ^ a b c d e Chen, Ruihong; Wang, Fang; Tang, Chunying; Zhang, Yong; Jia, Dingxian (2013-06-17). "Heterometallic Clusters [CuSn 3 S 9 ] 5− and [Cu 6 Sn 6 S 20 ] 10−: Solvothermal Synthesis and Characterization of 4f-3d Thiostannates". Chemistry – A European Journal. 19 (25): 8199–8206. doi:10.1002/chem.201300044. PMID 23616420.
- ^ a b Tan, Xiao-Feng; Liu, Xing; Zhou, Jian; Zhu, Ligang; Zhao, Rongqing; Huang, Qian (January 2016). "Two Quaternary Copper Thiostannates with Lanthanum(III) Complexes". Journal of Cluster Science. 27 (1): 257–265. doi:10.1007/s10876-015-0927-1. ISSN 1040-7278. S2CID 93262656.
- ^ Llanos, Jaime; Mujica, Carlos; Sánchez, Vı́ctor; Peña, Octavio (June 2003). "Physical and optical properties of the quaternary sulfides SrCu2MS4 and EuCu2MS4 (M=Ge and Sn)". Journal of Solid State Chemistry. 173 (1): 78–82. Bibcode:2003JSSCh.173...78L. doi:10.1016/S0022-4596(03)00093-8.
- ^ Aitken, Jennifer A.; Lekse, Jonathan W.; Yao, Jin-Lei; Quinones, Rosalynn (January 2009). "Synthesis, structure and physicochemical characterization of a noncentrosymmetric, quaternary thiostannate: EuCu2SnS4". Journal of Solid State Chemistry. 182 (1): 141–146. Bibcode:2009JSSCh.182..141A. doi:10.1016/j.jssc.2008.09.022.
- ^ a b c Han, Jingyu; Liu, Yun; Lu, Jialin; Tang, Chunying; Wang, Fang; Shen, Yali; Zhang, Yong; Jia, Dingxian (July 2015). "Heterometallic sulfide cluster [Ag6Sn6S20]10−: Solvothermal syntheses and characterizations of silver thiostannates with lanthanide complex counter cations". Inorganic Chemistry Communications. 57: 18–21. doi:10.1016/j.inoche.2015.04.018.
- ^ "Kiddcreekite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Bowlesite". www.mindat.org. Retrieved 2021-07-15.
- ^ a b c d Teske, Christoph Ludwig; Terraschke, Huayna; Mangelsen, Sebastian; Bensch, Wolfgang (2020-11-15). "Re-investigation of Barium-Gold(I)-Tetra-Thiostannate(IV), Ba[Au 2 SnS 4 ], with Short Au I ···Au I Separation Showing Luminescence Properties". Zeitschrift für anorganische und allgemeine Chemie. 646 (21): 1716–1721. doi:10.1002/zaac.202000306. ISSN 0044-2313.
- ^ Reshak, A.H.; Azam, Sikander (November 2014). "Linear and nonlinear optical properties of α-K2Hg3Ge2S8 and α-K2Hg3Sn2S8 compounds". Optical Materials. 37: 97–103. Bibcode:2014OptMa..37...97R. doi:10.1016/j.optmat.2014.05.006.
- ^ "Velikite". www.mindat.org. Retrieved 2021-07-08.
- ^ a b Guo, Yangwu; Liang, Fei; Li, Zhuang; Xing, Wenhao; Lin, Zhe-shuai; Yao, Jiyong; Mar, Arthur; Wu, Yicheng (2019-08-05). "AHgSnQ 4 (A = Sr, Ba; Q = S, Se): A Series of Hg-Based Infrared Nonlinear-Optical Materials with Strong Second-Harmonic-Generation Response and Good Phase Matchability". Inorganic Chemistry. 58 (15): 10390–10398. doi:10.1021/acs.inorgchem.9b01572. ISSN 0020-1669. PMID 31342744. S2CID 198494837.
- ^ Xing, Wenhao; Tang, Chunlan; Wang, Naizheng; Li, Chunxiao; Li, Zhuang; Wu, Jieyun; Lin, Zheshuai; Yao, Jiyong; Yin, Wenlong; Kang, Bin (2020-12-21). "EuHgGeSe 4 and EuHgSnS 4: Two Quaternary Eu-Based Infrared Nonlinear Optical Materials with Strong Second-Harmonic-Generation Responses". Inorganic Chemistry. 59 (24): 18452–18460. doi:10.1021/acs.inorgchem.0c03176. ISSN 0020-1669. PMID 33256399. S2CID 227245551.
- ^ "Coiraite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Franckeite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Ramosite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Cylindrite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Incaite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Plumbostannite". www.mindat.org. Retrieved 2021-07-15.
- ^ Abudurusuli, Ailijiang; Ding, Hanqin; Wu, Kui (November 2017). "Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se13". Journal of Solid State Chemistry. 255: 133–138. Bibcode:2017JSSCh.255..133A. doi:10.1016/j.jssc.2017.08.019.
- ^ "Abramovite". www.mindat.org. Retrieved 2021-07-15.
- ^ "Lévyclaudite". www.mindat.org. Retrieved 2021-07-15.
- v
- t
- e
H2S | He | ||||||||||||||||||||
Li2S | BeS | B2S3 +BO3 | CS2 COS | (NH4)SH | O | F | Ne | ||||||||||||||
Na2S | MgS | Al2S3 | SiS SiS2 -Si | PxSy -P | -S2− 2 | Cl | Ar | ||||||||||||||
K2S | CaS | ScS Sc2S3 | TiS TiS2 Ti2S3 TiS3 | VS VS2 V2S3 | CrS Cr2S3 | MnS MnS2 | FeS Fe3S4 | CoS | NiS | Cu2S CuS | ZnS | GaS Ga2S3 | GeS GeS2 -Ge | As2S3 As4S3 -As | SeS2 +Se | Br | Kr | ||||
Rb2S | SrS | Y2S3 | ZrS2 | NbS2 | MoS2 MoS3 | TcS2 Tc2S7 | Ru | Rh2S3 | PdS | Ag2S | CdS | In2S3 | SnS SnS2 -Sn | Sb2S3 Sb2S5 -Sb | TeS2 | I | Xe | ||||
Cs2S | BaS | * | LuS Lu2S3 | HfS2 | TaS2 | WS2 WS3 | ReS2 Re2S7 | OsS 4 | Ir2S3 IrS2 | PtS PtS2 | Au2S Au2S3 | HgS | Tl2S | PbS PbS2 | Bi2S3 | PoS | At | Rn | |||
Fr | Ra | ** | Lr | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
* | LaS La2S3 | CeS Ce2S3 | PrS Pr2S3 | NdS Nd2S3 | PmS Pm2S3 | SmS Sm2S3 | EuS Eu2S3 | GdS Gd2S3 | TbS Tb2S3 | DyS Dy2S3 | HoS Ho2S3 | ErS Er2S3 | TmS Tm2S3 | YbS Yb2S3 | |||||||
** | Ac2S3 | ThS2 | Pa | US US2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No |